| Introduction :
To compare data to known laws, it is important to represent the data mathematically. For example, when dealing with kinetics we are often concerned with the concentration of a substance. Measuring the concentration at several different times can yield a set of data which we need to represent with an equation rather than as separate points. To do this we use a process called linear least squares fitting. This process gives a linear fit in the slope-intercept form (y=mx+b). For a general linear equation, y = mx + b, it is assumed that the errors in the y-values are substantially greater than the errors in the x-values. The vertical deviation can be calculated using this formula: A short review of determinants:
Now, the values for m, b, and the deviation D can be determined by these matrices:
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Linear Least Squares Regression |