Ideal Gas Equation

It follows from the general description of the kinetic theory of gases that pressure, number of atoms of gas, volume and temperature are related parameters. For example, volume is the same for a mole of any gas at the same temperature and pressure.  Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules.  The molar volume of a gas ( volume occupied by 1 mole of gas) can be calculate from:
Molar Volume = V / n = 22.4 L at 0oC and 1 atm
n = 1 mole n = 1 mole n = 1 mole
P= 1 atm P= 1 atm P= 1 atm
T = 0o C (273 K) T = 0o C (273 K) T = 0o C (273 K)
V = 22.4 L V = 22.4 L 22.4 L
Mass = 4.003 g/mol Mass = 28.02 g 28.01 g

Since gas pressure is the result from collisions between gas particles and surfaces, anything that increases the number of collisions per unit of time will increase pressure.  Both increases in temperature and decreases in volume result in an increase in the number of collisions and therefore in gas pressure.  Increasing the number of gas particles without any changes in volume or temperature would also result in an increase in pressure.  ideal gas equation..





where P is pressure, V is volume, T is temperature and R is the the universal gas constant.   The value of the Universal Gas Constant depends on the units used for the remainder of the terms in the ideal gas equation.

Units for the Universal Gas Constant
R = 0.08206 atm * L/ mol * K

R = 62.36 torr * L / mol * K

R = 8.314 kPa * dm3 / mol * K

R = 8.314 J / mol 8 K    (J = joules)

A simple restatement of this equation, assuming that n, the number of moles of the gas remain constant, makes it possible to calculate P, V or T even when external conditions are changing. Take a look at this sample solution. Remember that STP means standard temperature and pressure, T = 0oC (273 Kelvin)  and P = 1 atm.


A ideal gas equation calculator is available online.


Quick Quiz: A tank with a fiexed volume of 438 L is filled with 0.885 kg of oxygen. Calculate the pressure of the oxgen at 21 degrees C.

2 atm
27.7 atm
1.53 atm
760 mmHg


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