Isotopes and Ions

Atoms that have the same number of protons, (Z), as an element but with a larger number of neutrons than the element has are called isotopes . Since neutrons are as massive as protons, the mass of an atom and its isotope(s) is(are) different. The atomic notations for the elemental form of carbon and its isotope C-14, (a carbon atom with 8 neutrons and 6 protons), are shown below. Isotopes are generally less stable than the atoms of their corresponding element. As a result, the nuclei of isotopes can undergo spontaneous radioactive decay in an effort to stabilize the atom. The decay process is accompanied by the release of high energy electromagnetic radiation like X-rays, and in some cases, by the ejection of sub-atomic particles such as electrons, protons, and neutrons. When the particle or particles ejected are protons, the isotope becomes a different element with a smaller number of protons. This process is called transmutation


Most chemical reactions take place when the electrons associated with different atoms that are in close proximity to each other begin to interact. Electrons that are farthest from the positively charged nucleus are the most likely to be involved in chemical reactions, and are referred to as valence electrons. In some case valence electrons can be pulled away from an atom by the strong attractive force coming from a nearby atom. The remaining altered atom now has one fewer electron than the neutral element, and so has a net positive charge. In fact, it is no longer an atom but rather, it is called an ion.  Ions with extra electrons can also form resulting in a net negative charge on the ion. Positively charged ions are also called cations, while negatively charged ions are called anions.

Quick Quiz: What is the difference between an anion and an isotope ?

an anion has a negative charge whereas an isotope has a positive charge
an isotope has more protons than electrons and an anion has more electrons than protons
an anion has an excess of electrons while an isotope has an excess of neutrons
none of the above


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